{ "item_title" : "Eta2 Complexes of Group 10 with Cinnamic Acid Derivatives", "item_author" : [" Magnus R. Buchner "], "item_description" : "Homogeneous catalysts based on transition metals are of high industrial relevance. An important goal for this purpose is the light-induced start of the catalytic reaction. The electronic and steric influence of the olefin ligand upon the spectroscopic properties, stability and reactivity of bistriphenylphosphine-cinnamate and related complexes of group 10 were studied in this thesis. By means of these findings a direct prediction of the reactivity was possible based on the NMR-spectroscopic behaviour. Thus a specific design of photo-switchable complexes was possible, in which the olefin ligand could be cleaved from the metal via a selective light-induced intra-ligand cyclisation. This ring closure was examined with the ligand itself as well as in the complexes, concerning electronic and steric influences.", "item_img_path" : "https://covers3.booksamillion.com/covers/bam/3/83/252/847/3832528474_b.jpg", "price_data" : { "retail_price" : "103.00", "online_price" : "103.00", "our_price" : "103.00", "club_price" : "103.00", "savings_pct" : "0", "savings_amt" : "0.00", "club_savings_pct" : "0", "club_savings_amt" : "0.00", "discount_pct" : "10", "store_price" : "" } }

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