Structure-Activity Correlations and Solid-State Kinetic Investigations of Iron Oxide-Based Catalysts Supported on Sba-15
Overview
In this book, iron oxidic species supported on nanostructured silica (SBA-15) are introduced as model catalysts for deducing structure-activity correlations in selective oxidation of propene. Influence of iron loading, Fe(III) precursor, powder layer thickness during calcination, and molybdenum addition on structure and activity of FexOy/SBA-15 catalysts is investigated. FexOy/SBA-15 catalysts are characterized ex situ and in situ by a multitude of analyzing methods, i.e. XRD, DR-UV-Vis spectroscopy, N2 physisorption, Raman and Mossbauer spectroscopy, GC-MS, X-ray absorption spectroscopy, and TPR. Moreover, applicability of solid-state kinetic analysis methods to supported iron oxidic species is shown. Results from solid-state kinetic analysis under non-isothermal conditions are particularly helpful in corroborating structure-activity correlations of FexOy/SBA-15 catalysts. Understanding the correlation of various synthesis parameters with structure and activity of FexOy/SBA-15 catalysts eventually permits obtaining improved green iron oxide catalysts for selective oxidation of propene.
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Details
- ISBN-13: 9783832549244
- ISBN-10: 3832549242
- Publisher: Logos Verlag Berlin
- Publish Date: October 2019
- Dimensions: 8.1 x 5.7 x 0.6 inches
- Shipping Weight: 0.75 pounds
- Page Count: 257
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